Oily soil detergency under microemulsion conditions: effects of oil loading and surfactant adsorption

Abstract

Detergency process of oily soil removal from fabrics is of interest and the mechanisms of oily soil removal are very complicated involving several factors: interfacial tension, oil loading and surfactant adsorption. In this study, the effects of oil loading and the surfactant adsorption on the detergency performance of oily soil removal were investigated. Mixed surfactant systems of branched alcohol propoxylate sulfate sodium salt (Alfoterra 145-3PO), an extended anionic surfactant, and secondary alcohol ethoxylate (Tergitol 15-S-5), a nonionic surfactant, were used to form microemulsions with motor oil. The CMC and CµC values of the mixed surfactants were 0.015 and 0.04 % total active mixed surfactants concentration, respectively. A polyester/cotton blend [65/35] was selected to use as a testing fabric in detergency experiments. The results showed that the oil loading and fabric weight did not affect the efficiency of oil removal. Furthermore, with the selected formulation (0.1 wt.% Alfoterra 145-3PO and 5 wt.% Tergitol 15-S-5), the oil detachment time was investigated at different temperatures (30-50°C) and different total surfactant concentrations (0.04-0.5 %). The results showed that surfactant concentration was found to decrease the oil detachment time, leading to increasing oil removal. But the temperature did not affect to the oil detachment time.